Uranium monophosphide

Uranium monophosphide
Identifiers
CAS Number
  • 12037-69-3 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 103867623
PubChem CID
  • 22899254
InChI
  • InChI=1S/P.U
    Key: UTHMXILCQVBCDM-UHFFFAOYSA-N
  • P#[U]
Properties
Chemical formula
UP
Molar mass 272.0625 g/mol
Density 10.23 g/cm3
Melting point 2,600 °C (4,710 °F; 2,870 K)
Structure
Crystal structure
Face-centered cubic
Lattice constant
a = 0.5578 nm
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound

Uranium monophosphide is a compound of uranium and phosphorus, synthesized from heating metal uranium and white phosphorus:

4 U + P 4 4 UP {\displaystyle {\ce {4U + P4->4UP}}}
It is a potential nuclear fuel.

In air, a thin glassy surface layer protects the compound from oxidation; over the course of months after synthesis, this layer develops a metallic sheen.

Further reading

  • Curry, N A (1966). "The magnetic structure of uranium monophosphide". Proceedings of the Physical Society. 89 (2): 427–429. Bibcode:1966PPS....89..427C. doi:10.1088/0370-1328/89/2/325.
  • Sidhu, S.S.; Vogelsang, W.; Anderson, K.D. (1966). "The antiferromagnetism of uranium monophosphide". Journal of Physics and Chemistry of Solids. 27 (8): 1197. Bibcode:1966JPCS...27.1197S. doi:10.1016/0022-3697(66)90001-1.
  • Assmann, Helmut; Stehle, Heinz (1981) [Mid-1979]. "Weitere Uranverbindungen als Kernbrennstoffe" [Other uranium compounds as nuclear fuels]. In Buschbeck, Karl-Christian; Keller, Cornelius (eds.). Handbuch der Anorganischen Chemie [Inorganic Chemistry Handbook]. Gmelin (in German). Vol. U: Uran (Suppl. A3) (8th ed.). Berlin: Springer. pp. 215–216. doi:10.1007/978-3-662-10275-6. ISBN 978-3-662-10276-3. LCCN 25-1383.
  • v
  • t
  • e
Uranium compounds
U(II)
U(III)
  • UF3
  • UCl3
  • UBr3
  • UI3
  • UP
  • U(OH)3
  • UH3
  • UN
Organouranium(III) compounds
  • U(C5H5)3
  • U(IV)
    • U(BH4)4
    • UC
    • UCl4
    • UF4
    • UBr4
    • UI4
    • UO2
    • UH4
    • USi2
    • US2
    • USe2
    • UTe2
    • U(SO4)2
    Organouranium(IV) compounds
  • U(C8H8)2
  • U(C5H5)4
  • U(C5H5)3Cl
  • U(IV,V)
    • U2N3
    U(IV,VI)
    • U3O8
    U(V)
    • UCl5
    • UF5
    • UBr5
    • UI5
    • U2O5
    U(VI)
    • (NH4)2U2O7
    • Na2U2O7
    • UCl6
    • UF6
    • U(PO4)2
    • UO3
    • UO4
    • UO2(CH3COO)2
    • UO2(CHO2)2
    • UO2CO3
    • UO2CO3·2(NH4)2CO3
    • UO2Cl2
    • UO2F2
    • UO2(NO3)2
    • UO2(OH)2
    • (UO2)2(OH)4
    • UO2(SO4)2
    • ZnUO2(CH3COO)4
    • UN2
    • H2UO4
    • Na4UO2(CO3)3
    U(XII)
    • UO6 (hypothetical)
    • v
    • t
    • e
    Binary phosphides
    PH3 He
    Li3P Be BP CP
    +C
    N +O F Ne
    Na3P Mg3P2 AlP +Si
    -SiP
    P S +Cl Ar
    K3P Ca3P2
    CaP
    ScP TiP V CrP
    Cr3P
    Mn FeP CoP
    Co2P
    Co3P2
    NixPy Cu3P Zn3P2
    ZnP2
    GaP -GeP AsP Se +Br Kr
    Rb Sr3P2 YP ZrP
    ZrP2
    NbP Mo3P
    MoP
    MoP2
    Tc Ru2P Rh Pd Ag3P Cd3P2 InP SnP3 SbP +Te +I Xe
    CsxPy Ba * LuP HfP Ta W Re OsP2 Ir PtP2 AuP Hg Tl PbP7 BiP Po At Rn
    Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
    * LaP CeP PrP
    PrP5
    NdP Pm SmP
    SmP5
    EuP GdP TbP DyP HoP ErP TmP YbP
    ** AcP ThP7 Pa UP NpP PuP Am Cm BkP Cf Es Fm Md No
    Ternary phosphides
    Quaternary phosphides
    Quinary phosphides
    See also